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Battery Guide |
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I. Battery Basics
The Science of
Batteries When you switch on a battery-powered device, such as a flashlight, electrons (negatively charged subatomic particles) begin to move quickly within each battery. Metal ions from the anode are “dissolved” into the electrolyte solution while hydrogen molecules from the electrolyte are deposited onto the cathode. Switching on the flashlight amounts to completing an electric circuit (pathway) that includes the battery terminals and the bulb. The current circulates through the battery and the flashlight, making the bulb work. When the anode has been fully “dissolved” or the cathode is fully reduced, the battery is considered to be discharged. Until this happens, a battery's active life depends on the amount of energy required to power the device as well as the type of metals used for its electrodes. Every metal or metallic compound has an electromotive force, which is the ability of the metal to gain or lose electrons in relation to another type of metal. The large the difference between the electromotive forces of the anode and cathode, the greater the amount of energy will be produced by the cell. Table 1.1 The Electromotive Series for Some Battery Components
Since a battery is one or more galvanic cells connected in series or in parallel, batteries can be made with almost any current at almost any voltage level. A battery composed of two 1.5V cells will produce 3V. A typical 9V battery is simply six 1.5V cells connected in a series. This type of series battery, however, will produce a current equivalent to just one of the galvanic cells. A battery composed of two 1.5V cells connected in parallel will still produce a voltage of 1.5V but the current can be double the current of just one cell – thereby providing a current twice as long as a single cell. Basic Battery Terminology Rechargeable or Secondary are terms used most often with specific devices such as laptop computers, answering machines or cell phones. These batteries can be re-charged and re-used when the chemical charge is exhausted. How? The electrodes contain chemicals that can be “revived” by reversing the electrochemical reaction that produces power. When such a battery is placed into a recharging unit, the charger sends a reverse current through the electrodes. The reverse current is delivered at a higher voltage, which is used to re-form the chemicals at each electrode. Once the battery voltage is increased to its charged state, it can be removed and used again. Wet Cell is a term that describes the battery’s electrolyte fluid which, in this case is thinner and more liquid in form. Wet cell batteries are often sensitive to the battery’s orientation and if positioned incorrectly, may not be able to produce a current if gas pockets form around an electrode. Vehicle batteries are almost always wet cells. Dry Cell is a term that describes a more solid, paste-like or powdery electrolyte material in a battery. Orientation is not a factor in dry cell batteries. Acid batteries get their name because of the type of electrolyte used in their construction. Acid-based batteries most often use sulphuric acid as the major component and are most often found used in vehicles. Alkaline batteries typically use sodium hydroxide or potassium hydroxide as the main component in the electrolyte make up. Alkaline batteries are mostly used where high-energy output is needed, such as cell phones, portable CD player, radios, pagers and cameras. Types of Disposable Batteries 2. Carbon-zinc batteries, also called standard carbon batteries, have electrodes made of zinc and carbon. An acidic paste between the electrodes serves as the electrolyte. Pros: Least expensive and have a long shelf life. Cons: Poor performance at lower temperatures, and performance diminishes as power drains from the battery. They have a propensity to leak because of the casing and can ruin the devices they are in. Note: Household items such as flashlights, radios, and remote controls typically use alkaline or carbon-zinc batteries. Because they last from five to eight times longer, alkaline batteries may be more economical than carbon-zinc batteries for devices that require high amounts of currents. 3. Lithium batteries have lithium metal anodes and produce more than twice the voltage of an alkaline cell. They are used in cameras, pacemakers, watches, and calculators because they have a very long service life in these low power devices. Lithium batteries weigh less than alkalines, which saves you 1 ounce for every 4 AA batteries. Pros: Lithium batteries provide a high power output, long shelf-life, and low temperature performance. They are small and light weight. Cons: High cost and the energy supply can be drained quickly in high-energy devices. 4. Air batteries have a zinc anode and a potassium hydroxide electrolyte. Because an air battery requires oxygen from the air or atmosphere for its electrochemical reaction to occur, it can operate only where the atmosphere is controlled. Air batteries are commonly used in hearing aids because the humidity and temperature within the ear canal remain constant. Pros: High energy output and long service life. They can only operate in a controlled atmosphere, and provide low power. Cons: Only designed for very small devices and usually are button sized. Benefits of using disposable batteries:
Drawbacks of using disposable batteries:
Note: Forget the hype about Super Titanium, E3 or any other new and over-advertised alkaline technology. They cost more and once used, still go in the garbage. Slightly longer active life is not offset by the cost and in the end, the battery companies are just making a lot of money off their strategic ad campaigns. Types of Rechargeable Batteries 2. Rechargeable Alkaline Batteries are made only by Rayovac and marketed to be rechargeable 25 times or more. Pros: The manufacturer states that its batteries do not suffer from “memory loss” that NiCd batteries do and that the shelf life is as long as disposable alkaline batteries. Cons: Unknown at this time. 3. Nickle-metal-hydride (Ni-MH) batteries use a nickle-hydroxide cathode, an alloy of a rare earth metal (M) with nickel for its anode and a potassium hydroxide solution for the electrolyte. These are a good replacement for alkalines. They are more expensive and have a shorter service life than NiCd. Pros: They can store large amounts of energy. Cons: Self-discharge quickly, and easily damaged by overcharging. 4. Lithium-ion batteries use an anode made of any one of a number of carbon-based materials. The cathode is made of a cobalt, manganese, or nickel oxide that includes lithium. They require special circuitry to help keep them from exploding, which is why general-purpose Li-ion cells are not commercially available in standard sizes like AA , C or D cell. Pros: Lithium offers the highest energy-producing potential at the lightest weight. Cons: They have a high cost, diminishing performance as power drains from the battery, and can explode if misused. 5. Nickel-Iron (Ni-I) are sometimes called the Edison battery and are much less expensive to build and to dispose of than nickel-cadmium cells. They are widely used in industrial settings and in eastern Europe where iron and nickel are readily available and inexpensive. Pros: The cells are rugged and reliable. Cons: They do not charge very well. Benefits of using rechargeable batteries:
Drawbacks of using rechargeable batteries:
II. Battery Size Our Battery DoctrineWhether you chose disposable or rechargeable batteries, we strongly support “battery size standardization” for practicality, and choose AA as the most universal size. By compiling gear powered exclusively by AA batteries, a soldier can triage his/her gear and replace any/all batteries more quickly and efficiently. All battery-powered gear on our site follows this standardization doctrine. Table 2.1 Battery Stats
Why AA? Compare the size, weight, and capacity of the standard batteries listed in Table 2.1. Relative to their weight, AA batteries have the best characteristics when compared to these other battery sizes. Also, there are adapters that hold AA batteries which enable you to use them in devices that normally require larger batteries. It is estimated that 90% of portable, battery-operated devices require AA, C, or D battery sizes.
III. Battery Advice
Because batteries are so common, we may forget that they are self-contained chemical reactors and that their contents can be harmful under certain circumstances. The chemicals that provide the battery's energy source are safely sealed within a metal or plastic container at the factory. Over time, however, battery casings may develop leaks because of abuse or degradation. Leaking batteries should never be used and should be discarded as soon as proper disposal can be arranged. Certain types of batteries may explode if they overheat. To protect yourself, never recharge a disposable battery. Batteries should never be exposed to open flames, disposed of in fires of incinerators, or stored in areas where the temperature may exceed 37°C. Batteries should likewise be kept free from moisture, which may cause a metal battery casing to corrode and leak. You should never carry a battery loose in your pocket, as contact with coins or other metal objects may cause the battery to short-circuit and overheat. If a manufacturer recommends a particular type of battery for a battery operated device, never use any other type of battery. Never Mix batteries from different manufacturers. Never mix batteries of different capacities. Never mix batteries of different chemistries. i.e. NiCD, NiMH, Lithium,etc. Batteries that are no longer useful should not be stored together. While they may lack sufficient charge to power their intended devices, drained batteries nonetheless retain some energy. If they come into contact with one another, they could generate enough heat to become a fire hazard. Newer NiMH battery chargers are designed to specifically charge NiMH and NiCad chemistries. However most of the older NiCad chargers were not designed to charge any other battery chemistries such as NiMH since they were unavailable at that time these chargers were designed. That is why many of the newer NiMH/NiCad chargers are capable of automatically charging both types, while others have a switch.
Batteries Storage Tips for Field Use Do not throw away dead or weak batteries. Heat can speed-up any remaining chemical reaction. Small batteries can gain life by warming them in your arm pit or between your legs. A larger battery can gain life by sleeping with the battery next to the body. Additional life can also be gained by placing batteries in the sun. Keep spare batteries handy so you can make a switch when the ones in your gear start to fade. When you remove batteries from your gear, put them in an inside shirt pocket to warm up. After a while, they'll regain their punch. If you won't be using your gear right away, don't install the batteries. Keep them warm as long as you can. If you warm batteries in a heated place, watch for sweating. Wipe off any moisture or it will freeze when you go back into the cold. Finally, if your gear has plastic pins in the battery compartment, take care when installing the battery. Cold pins become brittle. They'll break if handled too roughly. AA batteries of different chemistry are not compatible. Also, if you replace one battery, replace them all. A weak battery not pulling its load will cause the others to drain more rapidly. Common to all types of rechargeable batteries is a thing called "self discharge" where the battery actually loses power even though the device it's in is turned off. We don't know the exact rate of self discharge (it varies between capacity and battery chemistry) - but it is something you should be aware of. If you leave your camera sitting in a bag for long periods of time the NiMH batteries will not have much power left.
Fast vs. Standard Chargers Basically, fast charging units supply the batteries with more power at higher rates. The batteries thereby charge faster but may suffer more wear and tear. On the other hand, standard charging units charge batteries with less power at slower rates, thereby causing less wear and tear on the batteries. In the end, there is no noticeable difference in the battery performance. Nor can we determine a difference in the number of charges you can expect from each unit.
IV. Our Recommendations Disposables We strongly encourage the exclusive use of Lithium batteries for gear that has a low power draw (like LED flashlights). This will reduce the number of times you'll have to change batteries. Lithium batteries are: much lighter; last longer; more resistant to cold; have better shelf-life; and withstand heavier current draws. They are five times as expensive, but when you really need them, believe us, it will be worth it. Alkaline batteries are fine and dandy for home use, but switching to Lithium before taking your light source to the field will increase the battery life10-25%.
Rechargeables Table 2.2 AA Battery Stats
Chargers
Keeping "Current" In this modern day of portable electronic devices, the biggest limiting factor is battery life. As the field of material engineering continues to grow, so will the limits of battery life. Check this site often for updates to battery life technology. V. The Power Frontier Oxyrides Panasonic says it uses a patented process and a combination of new and improved electrolytes to manufacture the new AA and AAA cells. After eight years in development, they finally reached store shelves in Japan in 2007. Oxyrides face some competition in the disposable arena from long-lived AA and AAA lithium disposable batteries. But these batteries also cost about three times as much as alkalines. Given their relatively low price and their sizable power boost. Oxyrides should hold greater appeal for many battery buyers. There's one slight catch: At least for now, you can get the batteries only from Panasonic; the company has no plans at present to license its technology to others. Capacitors A capacitor-powered gadget could be charged in minutes or seconds instead of hours. And since capacitors can be reused indefinitely, environmental waste from discarded batteries would become a thing of the past. Delta Gear predicts that battery free bliss will be here by 2015.
Germs |
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